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the grain structure of metal has slip planes, imperfections or voids which fall in the general catagory of dislocations. A dislocation is the first thing to fail when any force is put onto the metal, but grain bounderies can stop these dislocations from moving.
To combat this, you need to increase grain boudary area meaning the smaller more compact the grains that are close together, the stronger it will be. Smaller grains = more stronger, ductile metal. larger grains = brittle
When you heat treat a metal, the grains are melted,rearranged and settled, but the longer the heat is present the larger the grains will grow, thus if you know the exact properties of metal you can control heat, time and cooling to extract the exact properties you want out of the metal.
Shot peening is basically shooting BB's at the metal to compact the grain structure. This mostly relives residual stresses that are present on the surface! The benefit of this is that no heat is involved thus less money, but the depth of the compaction is no where near heat treatment.
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